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4028-23-3 - Allylchlorodimethylsilane, 95% - ADMSCl - Allyldimethylchlorosilane - B22237 - Alfa Aesar

B22237 Allylchlorodimethylsilane, 95%

CAS-Nummer
4028-23-3
Synonyme
ADMSCl
Allyldimethylchlorosilane

Größe Preis ($) Menge Verfügbarkeit
5g 49,14
10g 96,31
25g 202,91
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Allylchlorodimethylsilane, 95%

MDL
MFCD00000506
EINECS
223-706-2

Chemische Eigenschaften

Formel
C5H11ClSi
Molmasse
134.68
Siedepunkt
110-112°
Flammpunkt
5°(41°F)
Dichte
0.896
Brechungsindex
1.4290
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in most organic solvents; reacts with alcohols, amines, and water.

Anwendungen

Allylchlorodimethylsilane is used in the synthesis of cyclo-1,1?,4,4?-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene, silylating agent for steroids for analysis by GC-MS. Also used in the preparation of phenylenebis(silanediyl triflates), useful synthons for organosilicon polymers, O-silylation of phenyl sulfones.

Bemerkungen

Moisture sensitive. Store away from strong oxidizing agents, strong bases, water/ moisture.

Literaturverweise

K. A. Abboud; D. W. Smith Jnr and K. B. Wagener. 3Structure of cyclo-1,1',4,4'-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene. Acta Cryst.. 1993, 53 (49), 1845-1848.

Yoshimoto Abe; Takahiro Gunji. Oligo- and polysiloxanes. Progress in Polymer Science. 2004, 29 (3), 149-182.

Reagent for the derivatization of steroids for GC-MS: J. Chromat., 129, 384 (1976); J. Chromat. Sci., 17, 115 (1979). See Appendix 4.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1737978
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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