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27489-62-9 - trans-4-Aminocyclohexanol, 98+% - trans-4-Hydroxycyclohexylamine - B22365 - Alfa Aesar

B22365 trans-4-Aminocyclohexanol, 98+%

CAS-Nummer
27489-62-9
Synonyme
trans-4-Hydroxycyclohexylamine

Größe Preis ($) Menge Verfügbarkeit
5g 35,10
25g 118,80
100g 354,60
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trans-4-Aminocyclohexanol, 98+%

MDL
MFCD00067698
EINECS
248-492-8

Chemische Eigenschaften

Formel
C6H13NO
Molmasse
115.18
Schmelzpunkt
110-113°
Sensitivität
Air Sensitive
Löslichkeit
Soluble in water.

Anwendungen

trans-4-Aminocyclohexanol is used as raw material in organic synthesis and is an important intermediate in the synthesis of drugs such as Ambroxol hydrochloride. It can react with butyric acid-(2-chloro-ethyl ester) to get butyric acid 4-amino-cyclohexyl ester. This reaction needs catalytic agent Aspergillus niger lipase and solvent 2-methyl-butan-2-ol.

Bemerkungen

Air Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literaturverweise

Thomas P. Johnston.; George S. McCaleb.; John A. Montgomery. Synthesis and biologic evaluation of major metabolites of N-(2-chloroethyl)-N'-cyclohexyl-N-nitrosourea. J. Med. Chem. 1975, 18, (6), 634-637.

Jie Cheng.; Mark L. Trudell. Synthesis of N-Heteroaryl-7-azabicyclo[2.2.1]heptane Derivatives via Palladium-Bisimidazol-2-ylidene Complex Catalyzed Amination Reactions. Org. Lett.2001, 3, (9), 1371-1374.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2922.19
TSCA
No

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