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563-76-8 - 2-Bromopropionyl bromide, 97% - B22504 - Alfa Aesar

B22504 2-Bromopropionyl bromide, 97%

CAS-Nummer
563-76-8
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100g 38,70
500g 137,00
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2-Bromopropionyl bromide, 97%

MDL
MFCD00000142
EINECS
209-261-7

Chemische Eigenschaften

Formel
CH3CHBrCOBr
Molmasse
215.88
Siedepunkt
48-50°/10mm
Flammpunkt
>110°(230°F)
Dichte
2.061
Brechungsindex
1.5210
Sensitivität
Moisture Sensitive
Löslichkeit
Miscible with trichloromethane, diethyl ether, benzene and acetone.

Anwendungen

2-Bromopropionyl bromide is used in the preparation of cellulose macroinitiator through direct acylation of cellulose in ionic liquid 1-allyl-3-methylimidazolium chloride. It is also used to prepare 3-(2-bromopropionyl)-2-oxazolidone derivatives and bromoester terminated poly(3-hexylthiophene). Further, it is used as a macroinitiator for atom transfer radical polymerization of acrylates.

Bemerkungen

Incompatible with water, alcohols, oxidizing agents and strong alkalis.

Literaturverweise

Xue, X.; Yang, J.; Huang, W.; Yang, H.; Jiang, B. Synthesis of Hyperbranched Poly(epsilon-caprolactone) Containing Terminal Azobenzene Structure via Combined Ring-Opening Polymerization and “Click” Chemistry. Polymers 2015, 7 (7), 1248-1268.

Huang, X.; Zhang, N.; Ban, L.; Su, H. Synthesis of Star Poly(N-isopropylacrylamide) with a Core of Cucurbit[6]uril via ATRP and Controlled Thermoresponsivity. Macromol. Rapid Commun. 2015, 36 (3), 311-318.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1071331
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2915.90
TSCA
Yes

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