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122-79-2 - Phenyl acetate, 99% - Acetic acid phenyl ester - B22561 - Alfa Aesar

B22561 Phenyl acetate, 99%

CAS-Nummer
122-79-2
Synonyme
Acetic acid phenyl ester

Größe Preis ($) Menge Verfügbarkeit
250g 32,96
1000g 104,03
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Phenyl acetate, 99%

MDL
MFCD00008699
EINECS
204-575-0

Chemische Eigenschaften

Formel
CH3CO2C6H5
Molmasse
136.15
Siedepunkt
195-196°
Flammpunkt
76°(168°F)
Dichte
1.075
Brechungsindex
1.5020
Löslichkeit
Soluble in water (4 g/L at 20°C).

Anwendungen

Phenyl acetate levels in urine are marker for the diagnosis of some forms of unipolar major depressive disorders. It undergoes Fries rearrangement to form a mixture of o- and p-hydroxyacetophenones which are useful intermediates in manufacture of pharmaceuticals. It is a metabolite of Phenylbutyrate (PB), useful in the treatment of neuroblastoma and lung cancer. An odorant found in strawberries, passion fruit and black tea.

Bemerkungen

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literaturverweise

H.C.Sabelli; J.Fawcett; F.Gusovsky; J.Javaid; J.Edwards; H.Jeffriess. Urinary phenyl acetate: a diagnostic test for depression? Science. 1983, 220,(4602), 1187-1188.

 

F.Jayat; M.J.Sabater Picot; M.Guisnet. Solvent effects in liquid phase Fries rearrangement of phenyl acetate over a HBEA zeolite. Catalysis Letters. 1996, 41,(3), 181-187.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302-H227

Harmful if swallowed. Combustible liquid.

Sicherheitshinweise: P210-P280-P264-P270-P301+P312-P330-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,7267
Beilstein
636458
Harmonized Tariff Code
2915.39
TSCA
Yes
RTECS
AJ2800000

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