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90-14-2 - 1-Iodonaphthalene, 98% - B22644 - Alfa Aesar

B22644 1-Iodonaphthalene, 98%

CAS-Nummer
90-14-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
10g 53,47
50g 201,15
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1-Iodonaphthalene, 98%

MDL
MFCD00003876
EINECS
201-968-9

Chemische Eigenschaften

Formel
C10H7I
Molmasse
254.07
Schmelzpunkt
Siedepunkt
161-162°/15mm
Flammpunkt
>110°(230°F)
Dichte
1.738
Brechungsindex
1.7010
Sensitivität
Light Sensitive
Löslichkeit
Slightly soluble in water.

Anwendungen

1-Iodonaphthalene undergoes Pd catalyzed cross-coupling reaction (Stille reaction) with 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine to afford 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine.

Bemerkungen

Light sensitive. Incompatible with oxidizing agents.

Literaturverweise

G.Kothandaraman; D.W.Pratt; D.S.Tinti. Optically detected magnetic resonance spectra of the lowest triplet state of 1-iodonaphthalene in durene at zero and high magnetic fields. J. Chem. Phys. 1975, 63,(3), 3337.

 

Guillermo A.Lotz; Sara M.Palacios; Roberto A.Rossi. Stereoselective reaction of a chiral assisted amide enolate ion with 1-iodonaphthalene by the SRN1 mechanism. Tetrahedron Letters. 1994, 35,(42), 7711-7714.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1906415
Harmonized Tariff Code
2903.99
TSCA
Yes

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