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1609-47-8 - Diethyl dicarbonate, 97% - Diethyl oxydiformate - Diethyl pyrocarbonate - B22753 - Alfa Aesar

B22753 Diethyl dicarbonate, 97%

CAS-Nummer
1609-47-8
Synonyme
Diethyl oxydiformate
Diethyl pyrocarbonate

Größe Preis ($) Menge Verfügbarkeit
5g 22,77
25g 67,14
100g 216,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Diethyl dicarbonate, 97%

MDL
MFCD00009106
EINECS
216-542-8

Chemische Eigenschaften

Formel
C6H10O5
Molmasse
162.14
Siedepunkt
93-94°/18mm
Flammpunkt
69°(156°F)
Dichte
1.101
Brechungsindex
1.3980
Sensitivität
Moisture Sensitive
Löslichkeit
Miscible with chloroform, ethanol, esters, ketones and hydrocarbons. Slightly miscible with water.

Anwendungen

Ribonuclease inhibitorDiethyl dicarbonate acts as an inhibitor of ryanodine binding to ryanodine/calcium(II) receptor channel. It is useful for specific inactivation of nucleases during isolation of undegraded polynucleotides. Further, it inhibits platelet-activating factor acetyl hydrolase. In addition to this, it is involved in the modification reagent for His and Tyr residues in proteins.

Bemerkungen

Store in cool place. Incompatible with strong oxidizing agents, strong reducing agents, strong acids, strong bases and ammonia.

Literaturverweise

In the presence of the hindered base lithium dicyclohexylamide (from Dicyclohexyl­amine, A15671), ɑ -ethoxycarbonylation of ketones occurs to give ß -keto esters: Synthesis, 1014 (1984).

Dogandzhiyski, P.; Ghidini, A.; Danneberg, F.; Stro?mberg, R.; Go?bel, M. W. Studies on Tris(2-aminobenzimidazole)-PNA Based Artificial Nucleases: A Comparison of Two Analytical Techniques. Bioconjugate Chem. 2015, 26 (12), 2514-2519.

Zuldesmi, M.; Waki, A.; Kuroda, K.; Okido, M. Hydrothermal treatment of titanium alloys for the enhancement of osteoconductivity. Mater. Sci. Eng., C 2015, 49, 430-435.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302-H315-H319-H335-H227

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Sicherheitshinweise: P210-P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,7998
Beilstein
637031
Harmonized Tariff Code
2920.90
TSCA
Yes
RTECS
LQ9350000

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