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544-13-8 - Glutaronitrile, 99% - 1,3-Dicyanopropane - Pentanedinitrile - B23663 - Alfa Aesar

B23663 Glutaronitrile, 99%

CAS-Nummer
544-13-8
Synonyme
1,3-Dicyanopropane
Pentanedinitrile

Größe Preis ($) Menge Verfügbarkeit
10g 31,93
50g 91,05
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Glutaronitrile, 99%

MDL
MFCD00001970
EINECS
208-861-6

Chemische Eigenschaften

Formel
C5H6N2
Molmasse
94.12
Schmelzpunkt
-29°
Siedepunkt
286-288°
Flammpunkt
112°(234°F)
Dichte
0.990
Brechungsindex
1.4350
Sensitivität
Hygroscopic
Löslichkeit
Soluble in water, alcohol and chloroform.

Anwendungen

It can be used for the conversion, by exchange, of carboxylic acids to nitriles, by heating in the presence of phosphoric acid. The equilibrium is displaced by cyclization to glutarimide. It is also used in the preparation of dicarbonyl compounds.

Bemerkungen

Hygroscopic. Protect from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literaturverweise

Yaser Abu-Lebdeh, et al. New electrolytes based on glutaronitrile for high energy/power Li-ion batteries.J. Power Sources.,2009,189(1), 576-579.

Jae-Young Lee, et al. Characteristics of the DGEBA/MDA system modified with glutaronitrile.Mater. Chem. Phys.,1996,44(1), 74-78.

Can be used for the conversion, by exchange, of carboxylic acids to nitriles, by heating in the presence of phosphoric acid. The equilibrium is displaced by cyclization to glutarimide: J. Org. Chem., 36, 3050 (1971).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302

Harmful if swallowed.

Sicherheitshinweise: P264-P270-P301+P312-P330-P501a

Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,4474
Beilstein
1738385
Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2926.90
TSCA
Yes
RTECS
YI3500000

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