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37942-07-7 - 3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99% - 3,5-Di-tert-butylsalicylaldehyde - B23834 - Alfa Aesar

B23834 3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99%

CAS-Nummer
37942-07-7
Synonyme
3,5-Di-tert-butylsalicylaldehyde

Größe Preis ($) Menge Verfügbarkeit
5g 42,93
25g 156,60
100g 524,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99%

MDL
MFCD00191998
EINECS
000-000-0

Chemische Eigenschaften

Formel
C15H22O2
Molmasse
234.34
Schmelzpunkt
59-61°
Sensitivität
Air Sensitive
Löslichkeit
Soluble in DMSO and methanol.

Anwendungen

3,5-Di-tert-butyl-2-hydroxybenzaldehyde is used in the synthesis of Mn(III)-salen complex and its diamino precursor 5,6-diamino-5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-β-L-idofuranose, chiral Schiff base ligand for an enantioselective copper-catalyzed addition of phenyl acetylene to imines, chiral oxazolidine ligand for the enantioselective addition of diethyl zinc to aldehydes and tin Schiff base complexes with histidine analogues. It has antibacterial activity and is used in the preparation nickel complexes. It is structurally related to 3,5-di-t-butylcatechol (DTCAT) but is not as potent an activator of rat skeletal muscle ryanodine receptor Ca2+ channel (RyRC).

Bemerkungen

Air sensitive. Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literaturverweise

Yan S and Klemm D. Mild and efficient synthesis of 5, 6-diamino-5, 6-dideoxy-1, 2-O-isopropylidene-3- O -methyl-ß-l-idofuranose: precursor of the first carbohydrate-derived chiral Mn (III)-salen complex. Tetrahedron.,2002,58(50), 10065-10071.

Ariadna Garza-Ortiz, et al. Novel Organotin(IV) Schiff Base Complexes with Histidine Derivatives: Synthesis, Characterization, and Biological Activity.Bioinorg Chem Appl.,2013,2013(6), 502713.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1877810
Harmonized Tariff Code
2912.49
TSCA
No

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