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87-90-1 - Trichloroisocyanuric acid, 90+% - Isocyanuric chloride - Symclosene - B23906 - Alfa Aesar

B23906 Trichloroisocyanuric acid, 90+%

CAS-Nummer
87-90-1
Synonyme
Isocyanuric chloride
Symclosene

Größe Preis ($) Menge Verfügbarkeit
100g 19,67
500g 40,32
2500g 139,20
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Trichloroisocyanuric acid, 90+%

MDL
MFCD00006553
EINECS
201-782-8

Chemische Eigenschaften

Formel
C3Cl3N3O3
Molmasse
232.41
Schmelzpunkt
ca 245° dec.
Flammpunkt
>250°(482°F)
Dichte
2.07
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in chlorocarbon, acetonitrile, acetone, water (12 g/L).

Anwendungen

Trichloroisocyanuric acid was used as a disinfection reagent in the transformation of benzophenone-3 in chlorinated water. It was also used in the synthesis of 2-halomethylene-3-oxoketoximes. It is used as a bleaching agent in the textile industry, a reagent in organic synthesis.

Bemerkungen

Moisture sensitive. Store away from reducing agents, acids, bases, flammable substances, organic materials, light, water/ moisture.

Literaturverweise

Ulf Tilstam and Hilmar Weinmann. Trichloroisocyanuric Acid:? A Safe and Efficient Oxidant. Org. Proc. Res. Dev. 2002, 6 (4), 384-393.

Ardeshir Khazaei; Mohammad Ali Zolfigol; Amin Rostami; Arash Ghorbani Choghamarani. Trichloroisocyanuric acid (TCCA) as a mild and efficient catalyst for the trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) under heterogonous conditions. Catalysis Communications. 2007, 8 (3), 543-547.

Low-cost chlorinating and oxidizing agent; review: Org. Process Res. Dev., 6, 384 (2002). Aromatic compounds can be chlorinated either on the ring (ionic conditions) or on the side chain (free-radical conditions): J. Org. Chem., 35, 719 (1970). In the presence of BF3 etherate, ketones are ɑ-chlorinated at the more substituted position: Synth. Commun., 15, 385 (1985). In combination with pyridine, sulfides are selectively oxidized to sulfoxides: Synth. Commun., 31, 245 (2001), thiols to disulfides: Synth. Commun, 31, 1825 (2001), and secondary alcohols to ketones: Synth. Commun., 22, 1589 (1992). In the presence of methanol in acetonitrile, acetone or dichloromethane, the same reagent system converts aldehydes directly to methyl esters: Synth. Commun., 26, 2633 (1996). Effective co-oxidant for the TEMPO-catalyzed chemoselective oxidation of alcohols to aldehydes and ketones: Org. Lett., 3, 3041 (2001). In acetic acid, pyridines are converted to their N-oxides: Synth. Commun., 34, 247 (2004).

With NaNO2 and wet silica selective mononitration of phenols is accomplished under mild conditions: Synlett, 191 (2003). Effectively catalyzes both the protection and deprotection of alcohols as their tetrahydropyranyl ethers: Synth. Commun., 34, 3623 (2004).

For a brief feature on uses in synthesis, see: Synlett, 2265 (2005).

Note: Confusion with Cyanuric chloride, L03442, exists in some earlier Fieser references.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H272-H400-H410-H302-H319-H335

May intensify fire; oxidizer. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Harmful if swallowed. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P221-P210-P220-P261-P273-P280-P305+P351+P338-P304+P340-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,9641
Beilstein
202022
Gefahrenklasse
5.1
Verpackungsgruppe
II
Harmonized Tariff Code
2933.69
TSCA
Yes
RTECS
XZ1925000

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