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It can be used to produce (1-ethoxycyclopropyloxy)trimethylsilane by heating.
O. L. Epstein, et al. On the mechanism of titanium-catalyzed cyclopropanation of esters with aliphatic organomagnesium compounds. Deuterium distribution in the reaction products of (CD3)2CHMgBr with ethyl 3-chloropropionate in the presence of titanium tetraisopropoxide.Russ. Chem. Bull.,2000,49(2), 378-380.
Herbert C. Brown, et al. Improved procedure for the asymmetric reduction of prochiral ketones by B-3-pinanyl-9-borabicyclo[3.3.1]nonane.J. Org. Chem.,1982,47(8), 1606-1608.
Reductive cyclization with Na metal in the presence of TMS chloride gives a cyclopropanone acetal, which has been used as a precursor of 1-lithio-1-ethoxycyclopropane: Tetrahedron Lett., 25, 5851 (1984); Org. Synth. Coll., 7, 131 (1990):
Gefahrenhinweise (EU): H227-H315-H319-H335
Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.