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623-48-3 - Ethyl iodoacetate, 98% - Iodoacetic acid ethyl ester - B24177 - Alfa Aesar

B24177 Ethyl iodoacetate, 98%

CAS-Nummer
623-48-3
Synonyme
Iodoacetic acid ethyl ester

Größe Preis ($) Menge Verfügbarkeit
5g 56,10
25g 224,00
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Ethyl iodoacetate, 98%

MDL
MFCD00001081
EINECS
210-796-3

Chemische Eigenschaften

Formel
ICH2CO2CH2CH3
Molmasse
214
Siedepunkt
179-180°
Flammpunkt
76°(169°F)
Dichte
1.81
Brechungsindex
1.503
Sensitivität
Light Sensitive
Löslichkeit
Insoluble in water.

Anwendungen

Ethyl iodoacetate was used in the synthesis of trans-2,3-disubstituted indolines by reacting with 1-azido-2-allylbenzene derivatives via a diastereoselective radical cascade.

Bemerkungen

Light sensitive. Store in dark. Storage temperature is 2-8°C. Store away from oxidizing agents.

Literaturverweise

François Brucelle; Philippe Renaud. Synthesis of a leucomitosane via a diastereoselective radical cascade. Journal of Organic Chemistry. 2013, 78, (12), 6245-6252.

Pier Giorgio Cozzi; Alessandro Mignogna and Paola Vicennati. Dimethylzinc-Mediated, Oxidatively Promoted Reformatsky Reaction of Ethyl Iodoacetate with Aldehydes and Ketones. Advanced Synthesis & Catalysis. 2008, 300, (7-8), 975-978.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227-H300-H314-H318

Combustible liquid. Fatal if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P210u-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
741934
Gefahrenklasse
6.1
Verpackungsgruppe
II
Harmonized Tariff Code
2915.90
TSCA
Yes
RTECS
AI3575000

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