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4606-07-9 - Ethyl cyclopropanecarboxylate, 98% - Cyclopropanecarboxylic acid ethyl ester - B24870 - Alfa Aesar

B24870 Ethyl cyclopropanecarboxylate, 98%

CAS-Nummer
4606-07-9
Synonyme
Cyclopropanecarboxylic acid ethyl ester

Größe Preis ($) Menge Verfügbarkeit
25g 38,60
100g 92,60
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Ethyl cyclopropanecarboxylate, 98%

MDL
MFCD00001282
EINECS
225-010-4

Chemische Eigenschaften

Formel
C6H10O2
Molmasse
114.15
Siedepunkt
133-134°
Flammpunkt
18°(64°F)
Dichte
0.960
Brechungsindex
1.4200
Löslichkeit
Not miscible in water.

Anwendungen

Ethyl cyclopropanecarboxylate is a reagent used in the addition of cyclopropane. It acts as annulation reagent for the conversion of aromatics to 2-methylindanones under Friedel-Crafts conditions.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible materials are oxidizing agents.

Literaturverweise

Harold W. Pinnick; Stephen P. Brown; Elizabeth A. McLean; Linwood W. ZollerIII. Friedel-Crafts reactions of ethyl cyclopropanecarboxylate. J. Org. Chem.1981, 46, (18), 3758-3760.

Gary M. Lampman; Deane A. Horne; Gordon D. Hager. Convenient syntheses of cyclopropanecarboxylic acid, ethyl cyclopropanecarboxylate, cyclopropanecarbonitrile, and nitrocyclopropane. J. Chem. Eng. Data.1969, 14, (3), 396-397.

Annulation reagent for the conversion of aromatics to 2-methylindanones under Friedel-Crafts conditions: J. Am. Chem. Soc., 99, 5508 (1977); J. Org. Chem., 46, 3758 (1981):

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225

Highly flammable liquid and vapour.

Sicherheitshinweise: P210-P280a-P240-P241-P303+P361+P353-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2039752
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2916.20
TSCA
No

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