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It is used in preparation of four novel dinuclear half-titanocenes with meta- and orthoxylene bridges as new metallocenes. It was used in the synthesis of dissymmetrical bis-macro cyclic salt.
Murray V. Baker; David H. Brown; Valerie J. Hesler; Brian W. Skelton and Allan H. White. Synthesis of a Bis(N-heterocyclic carbene)palladium Complex via Oxidative Addition of a C-C Bond in a Biimidazolium Ion. Organometallics. 2007, 26 (2), 250-252.
Keiiti Sisido; Nobuo Kusano; Ryôzi Noyori; Yôko Nozaki; Masatosi Simosaka and Hitosi Nozaki. Polycondensation of xylylene dibromides by transition metals in water suspension. Journal of Polymer Science Part A: General Papers. 1963, 1 (6), 2101-2107.
Reductive coupling has been used in a relatively high-yielding route to [2,2]-m-cyclophanes: Chem. Lett., 13 (1989); J. Chem. Soc. Perkin 1, 2029 (1991).
Gefahrenhinweise (EU): H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor