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103-80-0 - Phenylacetyl chloride, 98% - B24987 - Alfa Aesar

B24987 Phenylacetyl chloride, 98%

CAS-Nummer
103-80-0
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100g 35,64
500g 113,20
1000g 214,17
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Phenylacetyl chloride, 98%

MDL
MFCD00000729
EINECS
203-146-5

Chemische Eigenschaften

Formel
C8H7ClO
Molmasse
154.60
Siedepunkt
225°
Flammpunkt
102°(215°F)
Dichte
1.168
Brechungsindex
1.5325
Sensitivität
Moisture Sensitive
Löslichkeit
Miscible with alcohol and ether.

Anwendungen

Phenylacetyl chloride is used in the preparation of 1,2-diphenyl-ethanone by reaction with iodobenzene using tetrabutylammonium tetrafluoroborate as a phase transfer catalyst. It is widely used in the chemical industry for manufacturing dyes and pharmaceutical products. It plays an important role in the preparation of penicillin. Further, it is used to prepare esters for flavorings.

Bemerkungen

Moisture sensitive. Store in a cool place.Incompatible with amines, most common metals, strong bases and strong oxidizing agents.

Literaturverweise

Tao, Y.; Han, L.; Li, X.; Han, Y.; Liu, Z. Conformational stability and vibrational study of phenylacetyl chloride. J. Phys. Org. Chem. 2015, 28 (11), 703-711.

Hesping, L.; Biswas, A.; Daniliuc, C. G.; Mück-Lichtenfeld, C.; Studer, A. Stereoselective Lewis base catalyzed formal 1,3-dipolar cycloaddition of azomethine imines with mixed anhydrides. Chem. Sci. 2015, 6 (2), 1252-1257.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
742254
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2916.39
TSCA
Yes

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