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4-Azabenzimidazole is used in the preparation of imidazo[4,5-b]pyridine 4-oxide. It is also used as a reagent to prepare benzoylmethyl-substituted azoles which are inhibitors of nitric oxide synthase with antioxidant properties.
Wang, L.; Liu, N.; Dai, B. Metal-free site-selective C-N bond-forming reaction of polyhalogenated pyridines and pyrimidines. RSC Adv. 2015, 5 (100), 82097-82111.
Luo, X.; Guo, Y.; Ding, F.; Zhao, H.; Cui, G.; Li, H.; Wang, C. Significant Improvements in CO2 Capture by Pyridine-Containing Anion-Functionalized Ionic Liquids through Multiple-Site Cooperative Interactions. Angew. Chem. Int. Ed. 2014, 53 (27), 7053-7057.