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Formyl anion equivalent. Self-condensation was found to compete with alkylation in the Stork LDA procedure, but the molecule was successfully used to introduce a formyl group by SN2' alkylation in the presence of K2CO3, in a synthesis of -cyclocitral: Tetrahedron Lett., 25, 3457 (1984):/n
For a review of the use of ɑ-dialkylaminonitriles as acyl anion equivalents, see: Tetrahedron, 39, 3207 (1983)./n
Gefahrenhinweise (EU): H226-H300-H310-H319
Flammable liquid and vapour. Fatal if swallowed. Fatal in contact with skin. Causes serious eye irritation.
Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor IF ON SKIN: Wash with plenty of water.