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3558-69-8 - 2,6-Diphenylpyridine, 97% - B25179 - Alfa Aesar

B25179 2,6-Diphenylpyridine, 97%

CAS-Nummer
3558-69-8
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 63,76
25g 271,92
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2,6-Diphenylpyridine, 97%

MDL
MFCD00006284
EINECS
222-620-2

Chemische Eigenschaften

Formel
C17H13N
Molmasse
231.30
Schmelzpunkt
74-81°
Siedepunkt
210°/3mm
Löslichkeit
Insoluble in water.

Anwendungen

2,6-Diphenylpyridine is used as a tridentate [C?N?C] dianionic ligand in organogold(III) chemistry, an intermediate. It readily adds an electron from alkali metals in THF to give a radical anion which is a powerful reducing agent.

Bemerkungen

Store in a cool, dry place in tightly closed container. Incompatible with oxidizing agents.

Literaturverweise

Matthew Polson; Sandro Fracasso; Valerio Bertolasi; Marcella Ravaglia; and Franco Scandola. Iridium Cyclometalated Complexes with Axial Symmetry. Synthesis and Photophysical Properties of a trans-Biscyclometalated Complex Containing the Terdentate Ligand 2,6-Diphenylpyridine. Inorg. Chem. 2004, 43 (6), 1950-1956.

Kar-Ho Wong; Kung-Kai Cheung; Michael Chi-Wang Chan; and Chi-Ming Che. Application of 2,6-Diphenylpyridine as a Tridentate [C?N?C] Dianionic Ligand in Organogold(III) Chemistry. Structural and Spectroscopic Properties of Mono- and Binuclear Transmetalated Gold(III) Complexes. Organometallics. 1998, 17 (16), 3505-3511.

Readily adds an electron from alkali metals in THF to give a radical anion which is a powerful reducing agent: e.g. reacting with benzophenone to give the dianion which can be carbonated with CO2 to give benzilic acid: Bull. Soc. Chim. Fr., 1710 (1960).

Weitere Referenzen

Beilstein
7516
Harmonized Tariff Code
2933.39
TSCA
No

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