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For general reactions of isocyanates, see Appendix 3./n
Has been used to protect the SH group of cysteine as the S-(N-ethylcarbamate). The group is stable to acid but can be readily cleaved with aqueous NaOH: Helv. Chim. Acta, 49, 83 (1966), or by Hg or Ag salts: J. Am. Chem. Soc., 94, 6170 (1972)./n
Gefahrenhinweise (EU): H225-H301-H330-H315-H319-H334-H335
Highly flammable liquid and vapour. Toxic if swallowed. Fatal if inhaled. Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation.
IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.