B25370 Ethyl 2-butynoate, 98%
SDS
| Stock No. | Größe | Preis ($) | Menge | Verfügbarkeit |
|---|---|---|---|---|
| B25370-03 | 1g | 22,20 |
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| B25370-06 | 5g | 69,10 |
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| B25370-14 | 25g | 291,00 |
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Ethyl 2-butynoate, 98%
Chemische Eigenschaften
Anwendungen
Ethyl 2-butynoate is used as a precursor for the synthesis of 3-ethyl, 1-methyl 1-(2-nitrophenyl)-cyclopent-3-ene-1,3-dicarboxylate, alkenylsilanols and tricyclic aziridine derivatives. It acts as a methanogenesis inhibitor. As an electron deficient alkyne derivative, it plays a vital role in the preparation of 1,3-dienes catalyzed by rhodium(I)/H8-BINAP complex.
Bemerkungen
Literaturverweise
Miyabe, H. Synthesis of Oxygen Heterocycles via Aromatic C-O Bond Formation Using Arynes. Molecules 2015, 20 (7), 12558-12575.
Liu, J.; Liu, H.; Na, R.; Wang, G.; Li, Z.; Yu, H.; Wang, M.; Zhong, J.; Guo, H. Phosphine-catalyzed [3 + 2] and [3 + 3] Annulations of Azomethine Imines with Ethyl 2-Butynoate. Chem. Lett. 2012, 41 (3), 218-220.
GHS Gefahren- und Sicherheitshinweise
Gefahrenhinweise (EU): H226-H315-H319-H335
Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Sicherheitshinweise: P261-P280g-P305+P351+P338
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
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