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B25385 (±)-2-Methyl-2-propanesulfinamide, 97%

CAS-Nummer
146374-27-8
Synonyme
(+/-)-tert-Butyl sulfinamide

Stock No. Größe Preis ($) Menge Verfügbarkeit
B25385-03 1g 46,80
B25385-06 5g 160,00
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(±)-2-Methyl-2-propanesulfinamide, 97%

MDL
MFCD05861480

Chemische Eigenschaften

Formel
(CH3)3CS(O)NH2
Molmasse
121.20
Schmelzpunkt
97-101°
Storage & Sensitivity
Ambient temperatures.
Löslichkeit
Soluble in methanol.

Anwendungen

(±)-2-Methyl-2-propanesulfinamide is used in the synthesis of 4-sulfonyliminopiperidine and its reaction with benzyl Grignard to form an important pharmaceutical building block, 4-benzyl-4-aminopiperidne. It is also used to prepare spiro tosylaziridines via methylene insertion into the derived sulfonylimine.

Bemerkungen

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literaturverweise

John J.Caldwell; Ian Collins. Rapid synthesis of 4-benzyl-4-aminopiperidines by addition of Grignard reagents to N-(1-boc-piperidin-4-ylidene)-tert-butanesulfinyl imine. Synlett. 2006, (16), 2565-2568.

 

Joanne Hannam; Timothy Harrison; Felicity Heath; Andrew Madin; Kevin Merchant. Rapid and selective synthesis of substituted 1,2,5-thiadiazolidine 1,1-dioxides. Synlett. 2006, (6), 833-836.

Weitere Referenzen

Harmonized Tariff Code
2930.90
TSCA
No

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Kürzlich angesehen

Chemikalien

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Metalle und Stoffe

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Forschungs- und Laborbedarf