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1711-02-0 - 4-Iodobenzoyl chloride, 98% - B25388 - Alfa Aesar

B25388 4-Iodobenzoyl chloride, 98%

CAS-Nummer
1711-02-0
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 59,12
25g 162,90
100g 509,40
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4-Iodobenzoyl chloride, 98%

MDL
MFCD00001058
EINECS
216-974-7

Chemische Eigenschaften

Formel
C7H4ClIO
Molmasse
266.47
Schmelzpunkt
61-65°
Siedepunkt
120-121°/1mm
Flammpunkt
>110°(230°F)
Sensitivität
Moisture & Light Sensitive
Löslichkeit
Soluble in toluene and benzene.

Anwendungen

4-Iodobenzoyl chloride is employed in the preparation of pyrroles by reaction with imines and acetylenes mediated by isocyanides using palladium catalysis. It is also used in the preparation of N-(1-benzylpyrrolidin-3-yl)arylbenzamides, potential human dopamine D<sub>4</sub> antagonists. Further, it is used to prepare [2]rotaxane monomer and poly[2] rotaxane. In addition to this, it is important in the modification of poly(allylamine) in order to make the polymer X-ray visible.

Bemerkungen

Moisture sensitive. Incompatible with strong bases and water.

Literaturverweise

Takahashi, Y.; Miura, Y.; Yoshioka, N. Introduction of Three Aryl Groups to Benzotriazinyl Radical by Suzuki-Miyaura Cross-coupling Reaction. Chem. Lett. 2014, 43 (8), 1236-1238.

Wang, Q.; Qian, K.; Liu, S.; Yang, Y.; Liang, B.; Zheng, C.; Yang, X.; Xu, H.; Shen, A. Q. X-ray Visible and Uniform Alginate Microspheres Loaded with in SituSynthesized BaSO4 Nanoparticles for in Vivo Transcatheter Arterial Embolization. Biomacromolecules 2015, 16 (4), 1240-1246.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P280-P305+P351+P338-P309-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

Weitere Referenzen

Beilstein
774718
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2916.39
TSCA
Yes

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