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74289-57-9 - Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90% - Bis(3,5-dimethylphenyl)chlorophosphine - Chlorodi(3,5-xylyl)phosphine - H25885 - Alfa Aesar

H25885 Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%

CAS-Nummer
74289-57-9
Synonyme
Bis(3,5-dimethylphenyl)chlorophosphine
Chlorodi(3,5-xylyl)phosphine

Größe Preis ($) Menge Verfügbarkeit
1g 81,90
5g 312,00
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Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%

MDL
MFCD01630841
EINECS
000-000-0

Chemische Eigenschaften

Formel
C16H18ClP
Molmasse
276.75
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Reacts with water.

Anwendungen

Chlorobis(3,5-dimethylphenyl)phosphine is used in the synthesis of (S)- and (R)-2,2?-Bis[bis(3,5-dimethylphenyl)phosphinoyl]-5,5?,6,6?,7,7?,8,8?-octahydro-1,1?-binaphthyl (Xyl-H 8 -BINAPO).

Bemerkungen

Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, bases.

Literaturverweise

Rongwei Guo,; Terry T.-L. Au-Yeung,; Jing Wu,; Michael C.K. Choi,;, Albert S.C. Chan. Modified BINAPO ligands for Rh-catalysed enantioselective hydrogenation of acetamidoacrylic acids and esters. Tetrahedron: Asymmetry. 2002, 13 (23), 2519-2522.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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