Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

1019-71-2 - Chlorodi(p-tolyl)phosphine, 95% - Di(p-tolyl)chlorophosphine - Chlorobis(4-methylphenyl)phosphine - H25889 - Alfa Aesar

H25889 Chlorodi(p-tolyl)phosphine, 95%

CAS-Nummer
1019-71-2
Synonyme
Di(p-tolyl)chlorophosphine
Chlorobis(4-methylphenyl)phosphine

Größe Preis ($) Menge Verfügbarkeit
1g 87,55
5g 305,91
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Chlorodi(p-tolyl)phosphine, 95%

MDL
MFCD01630844
EINECS
000-000-0

Chemische Eigenschaften

Formel
C14H14ClP
Molmasse
248.69
Siedepunkt
180-184°/10mm
Dichte
1.159
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Reacts with water.

Anwendungen

Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.

Bemerkungen

Air and moisture sensitive. Incompatible with oxidizing agents, water/ moisture.

Literaturverweise

Chi-Feng Lin; Iwao Ojima. Formal enantioselective total synthesis of schulzeines A-C via Pd-catalyzed intramolecular asymmetric allylic amination. Journal of Organic Chemistry. 2011, 76 (15), 6240-6249.

X. Ren; L. Wang and Y. Li. 1,1'-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene. Acta Cryst. 2012, 68, 922.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

Empfohlen

  • H25883

    Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals
  • H25885

    Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%
  • H25887

    Chlorobis(4-methoxyphenyl)phosphine, 98+%
  • H25888

    Chlorobis[4-(trifluoromethyl)phenyl]phosphine, 97%
  • H25890

    Chlorodi(o-tolyl)phosphine, 98%

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf