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36042-94-1 - Chlorodi(o-tolyl)phosphine, 98% - Di(o-tolyl)chlorophosphine - Chlorobis(2-methylphenyl)phosphine - H25890 - Alfa Aesar

H25890 Chlorodi(o-tolyl)phosphine, 98%

CAS-Nummer
36042-94-1
Synonyme
Di(o-tolyl)chlorophosphine
Chlorobis(2-methylphenyl)phosphine

Größe Preis ($) Menge Verfügbarkeit
1g 68,40
5g 225,00
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Chlorodi(o-tolyl)phosphine, 98%

MDL
MFCD04038733
EINECS
000-000-0

Chemische Eigenschaften

Formel
C14H14ClP
Molmasse
248.69
Schmelzpunkt
57°
Siedepunkt
174-178°/3mm
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Not miscible or difficult to mix in water.

Anwendungen

Chlorodi(o-tolyl)phosphine is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff.

Bemerkungen

Air and moisture sensitive. Incompatible with oxidizing agents, bases, water/ moisture.

Literaturverweise

Anthony G. Coyne; Helge Müller-Bunz; Patrick J. Guiry. The asymmetric synthesis of β-lactams: HETPHOX/Cu(I) mediated synthesis via the Kinugasa reaction. Tetrahedron: Asymmetry. 2007, 18 (2), 199-207.

Peter W. Clark; Bernard J. Mulraney. Synthesis and physical properties of chlorodi(o-totyl)phosphine, lithium di(o-totyl)2P(CH2)nP(o-totyl) (n ? 1-4, 6, 8). Journal of Organometallic Chemistry. 1981, 217 (1), 51-59.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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