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23719-80-4 - Cyclopropylmagnesium bromide, 0.5M-0.7M in THF - H26273 - Alfa Aesar

H26273 Cyclopropylmagnesium bromide, 0.5M-0.7M in THF

CAS-Nummer
23719-80-4
Synonyme

Größe Preis ($) Menge Verfügbarkeit
25ml 78,40
100ml 210,00
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Cyclopropylmagnesium bromide, 0.5M-0.7M in THF

MDL
MFCD00672094

Chemische Eigenschaften

Formel
C3H5BrMg
Molmasse
145.28
Flammpunkt
-17°(1°F)
Dichte
0.968
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Soluble in water (17 mg/ml), (25°C). Soluble in organic solvents.

Anwendungen

It often acts as the starting nutrient mix for dropout studies where fermentation conditions required the absence of one or more essential amino acids. For classifying Yeasts based on colonial characteristics and cell morphology.

Bemerkungen

Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air, water and moisture.

Literaturverweise

H. M. Walborsky,; Christoph Zimmermann.The surface nature of Grignard reagent formation. Cyclopropylmagnesium bromide. J. Am. Chem. Soc. 1992, 114 (13), 4996-5000.

Chutian Shu,; Kanwar Sidhu,; Li Zhang,; Xiao-jun Wang,; Dhileepkumar Krishnamurthy,; Chris H. Senanayake.Palladium-Catalyzed Cross-Coupling of Cyclopropylmagnesium Bromide with Aryl Bromides Mediated by Zinc Halide Additives . J. Org. Chem. 2010 , 74(19), 6677-6680.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H314-H351-H335

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation.

Sicherheitshinweise: P210-P260-P201-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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