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In many of the reactions, organozinc compounds appear as intermediates. Some of the synthetic uses of organozinc compounds are: for the stereo selective alkylation reaction of cyclic ketones, conjugate addition reaction to alpha, beta-unsaturated carbonyl compounds, ring opening reactions of epoxides and oxo vanadium-induced ligand coupling of aryltrimethyl zincates.
Knochel, P,; Singer, R. D. Preparation and Reactions of Polyfunctional Organozinc Reagents in Organic Synthesis. Chem. Rev. 1993, 93 2117-2188 .
Kim, S.-H.; Rieke, R. D. Recent Advance in Heterocyclic Organozinc and Organomanganese Compounds; Direct Synthetic Routes and Application in Organic Synthesis.Molecules. 2010, 15 8006-8038..
Gefahrenhinweise (EU): H225-H261-H302-H333-H314-H318-H351-H335
Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.
Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.