H26857 Trimethylsilyl 2,2-difluoro-2-(fluorosulfonyl)acetate, 94%
SDS
| Stock No. | Größe | Preis ($) | Menge | Verfügbarkeit |
|---|---|---|---|---|
| H26857-03 | 1g | 39,80 |
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| H26857-06 | 5g | 70,50 |
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| H26857-14 | 25g | 219,00 |
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Trimethylsilyl 2,2-difluoro-2-(fluorosulfonyl)acetate, 94%
Chemische Eigenschaften
Anwendungen
Trimethylsilyl 2,2-difluoro-2-(fluorosulfonyl)acetate is an fluoroalkylation agent, reactant for preparation of difluorocyclopropenes, preparation of difluorocarbene reagents.
Bemerkungen
Literaturverweise
Zhiyong Wang.; Richard B. Silverman. Trimethylsilyl 2,2-difluoro-2-(fluorosulfonyl)acetate. Bioorganic & Medicinal Chemistry. 2006, 14, (7), 2242-2252.
Kohsuke Aikawa.; Wataru Toya.; Yuzo Nakamura.; Koichi Mikami. Development of (Trifluoromethyl)zinc Reagent as Trifluoromethyl Anion and Difluorocarbene Sources. Org. Lett. 2015, 17, (20), 4996-4999.
GHS Gefahren- und Sicherheitshinweise
Gefahrenhinweise (EU): H226-H314-H318
Flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.
Sicherheitshinweise: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
