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12289-94-0 - Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) - (1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium(II) - Ruthenium(II) bis(2-methylallyl) 1,5-cyclooctadiene complex - H26891 - Alfa Aesar

H26891 Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

CAS-Nummer
12289-94-0
Synonyme
(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium(II)
Ruthenium(II) bis(2-methylallyl) 1,5-cyclooctadiene complex

Größe Preis ($) Menge Verfügbarkeit
1g 126,00
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Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

MDL
MFCD00216965

Chemische Eigenschaften

Formel
C16H26Ru
Molmasse
319.45
Schmelzpunkt
83-86°
Sensitivität
Air & Moisture Sensitive
Löslichkeit
It is soluble in water.

Anwendungen

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is used as a catalyst and pharmaceutical intermediate. It is also used as a precatalysts for asymmetric and Cross-Coupling Catalysis reactions, and in organic chemical synthesis.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away strong oxidizing agents.

Literaturverweise

A Fürstner.; OR Thiel.; L Ackermann. Ruthenium carbene complexes with N, N'-bis (mesityl) imidazol-2-ylidene ligands: RCM catalysts of extended scope. J. Org. Chem. 200065 (7), 2204-2207.

LJ Goossen.; M Arndt.; M Blanchot. A Practical and Effective Ruthenium Trichloride-Based Protocol for the Regio-and Stereoselective Catalytic Hydroamidation of Terminal Alkynes. J. Org. Chem. 2008350 (17), 2701-2707.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H261

In contact with water releases flammable gas.

Sicherheitshinweise: P231+P232-P280a-P370+P378c-P402+P404-P501a

Handle under inert gas. Protect from moisture. Wear protective gloves and eye/face protection. In case of fire: Use for extinction: CO2, sand, extinguishing powder. Store in a dry place. Store in a closed container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.3
Verpackungsgruppe
III
Harmonized Tariff Code
2843.90
TSCA
No

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