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30282-14-5 - 2-Hydroxycyclohexanone dimer, 90+% - Adipoin - H27199 - Alfa Aesar

H27199 2-Hydroxycyclohexanone dimer, 90+%

CAS-Nummer
30282-14-5
Synonyme
Adipoin

Größe Preis ($) Menge Verfügbarkeit
1g 21,22
5g 51,91
25g 118,80
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2-Hydroxycyclohexanone dimer, 90+%

MDL
MFCD00151157

Chemische Eigenschaften

Formel
C12H20O4
Molmasse
228.28
Schmelzpunkt
100-107°
Siedepunkt
83-86°/13mm
Flammpunkt
79°(174°F)
Löslichkeit
Partly miscible in water.

Anwendungen

It is a reactant involved in the synthesis of substrates for tin tetrachloride mediated fragmentation to produce ynones and ynoates, tandem oxidation coupling reactions with diamines, asymmetric allylic alkylation of enolates and formate reduction of allylic carbonates for polypropionate systems.

Bemerkungen

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep away from ignition sources. Protect from electrostatic charges. Ensure adequate ventilation.

Literaturverweise

Barry M Trost, et al. Enantioselective synthesis of alpha-tertiary hydroxyaldehydes by palladium-catalyzed asymmetric allylic alkylation of enolates.J Am Chem Soc.,2009,129(2), 282-3.

Ali Bayir, et al. Preparation of tethered aldehyde ynoates and ynones by ring fragmentation of cyclic gamma-oxy-beta-hydroxy-alpha-diazo carbonyls.J Org Chem.,2010,75(2), 296-302.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H228-H315-H319-H335

Flammable solid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P210-P280g-P305+P351+P338

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Gefahrenklasse
4.1
Verpackungsgruppe
III
Harmonized Tariff Code
2932.99
TSCA
No

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