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190003-81-7 - (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl - (R)-Xylyl-H8-BINAP - H27351 - Alfa Aesar

H27351 (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl

CAS-Nummer
190003-81-7
Synonyme
(R)-Xylyl-H8-BINAP

Größe Preis ($) Menge Verfügbarkeit
50mg 128,75
250mg 387,28
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(R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl

MDL
MFCD06796646

Chemische Eigenschaften

Formel
C52H56P2
Molmasse
742.97
Sensitivität
Air Sensitive
Löslichkeit
Insoluble in water.

Anwendungen

Used in the synthesis of organometallic catalysts. For coupling reactions, addition reactions, asymmetric hydrogenation, asymmetric hydroboration.

Bemerkungen

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air.

Literaturverweise

Jianrong (Steve) Zhou,; John F. Hartwig. Intermolecular, Catalytic Asymmetric Hydroamination of Bicyclic Alkenes and Dienes in High Yield and Enantioselectivity. J. Am. Chem. Soc. 2008 , 130 (37),12220-12221.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2931.90
TSCA
No

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