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50816-19-8 - 8-Bromo-1-octanol, 95% - Octamethylene bromohydrin - H27628 - Alfa Aesar

H27628 8-Bromo-1-octanol, 95%

CAS-Nummer
50816-19-8
Synonyme
Octamethylene bromohydrin

Größe Preis ($) Menge Verfügbarkeit
1g 42,75
5g 142,95
25g 464,53
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

8-Bromo-1-octanol, 95%

MDL
MFCD00010388
EINECS
256-785-7

Chemische Eigenschaften

Formel
C8H17BrO
Molmasse
209.13
Siedepunkt
79-80°/0.07mm
Flammpunkt
>110°(230°F)
Dichte
1.220
Brechungsindex
1.4810

Anwendungen

It is used to produce 8-phenylselanyl-octan-1-ol by reaction with diphenyl-diselane. The reaction occurs with reagent sodium borohydride and solvent ethanol at ambient temperature. The yield is about 96%. 8-Bromo-1-octanol was used in the synthesis of (E)-10-hydroxy-2-decenoic acid (royal jelly acid)1. It was also used in the synthesis of (Z)-14-methyl-9-pentadecenoic acid.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents. Refrigerated (4°C).

Literaturverweise

R Chiron. New synthesis of royal jelly acid.. Journal of Chemical Ecology. 1982, 8 (4), 709-713

Carballeira NM,; Sanabria D,;Oyola D. An improved synthesis for the (Z)-14-methyl-9-pentadecenoic acid and its topoisomerase I inhibitory activity. ARKIVOC. 2007, 8 (49-57).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319

Causes skin irritation. Causes serious eye irritation.

Sicherheitshinweise: P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P302+P352

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: IF ON SKIN: Wash with plenty of soap and water.

Weitere Referenzen

Beilstein
1900837
Harmonized Tariff Code
2905.59
TSCA
Yes

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