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4385-76-6 - 4-(4-Pyridyl)benzoic acid, 97% - H27882 - Alfa Aesar

H27882 4-(4-Pyridyl)benzoic acid, 97%

CAS-Nummer
4385-76-6
Synonyme

Größe Preis ($) Menge Verfügbarkeit
250mg 52,94
1g 125,66
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4-(4-Pyridyl)benzoic acid, 97%

MDL
MFCD04114574

Chemische Eigenschaften

Formel
C12H9NO2
Molmasse
199.20
Schmelzpunkt
>300°
Löslichkeit
Slightly soluble in water.

Anwendungen

Self-assembly of 4-(4-pyridyl)benzoic acid (pybenH), Ni2+, SCN- and an aromatic guest (naphthalene or dibenz[a,h]anthracene) gave two isostructural inclusion compounds, in which pybenH ligands form the corresponding dimers acting as bidentate building blocks with a length of ca. 20.86 Å. By replacing an isonicotinic acid dimer with a 4-(4-pyridyl)benzoic acid (pybenH) dimer, new inclusion compounds in which pybenH dimers function as bridging ligands of ca. 21 Å.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literaturverweise

Ryo Sekiya1),; Shin-ichi Nishikiori1),; Katsuyuki Ogura2). 4-(4-Pyridyl)benzoic Acid (PybenH) Dimer: An Efficient and Reasonable Design for a Long Linear Bidentate Building Block Employed in Metal-Organic Coordination Framework . Chemistry Letters. 2006, 35(6), 614-615.

Ryo Sekiya,; Shin-ichi Nishikiori. Structural Extension from an Isonicotinic Acid Dimer to 4-(4-Pyridyl)benzoic Acid (pybenH) Dimer: X-ray Crystal Structure Analysis and Inclusion Properties of a Hydrogen-Bonded Coordination Polymer [Ni(SCN)2(pybenH)2]. Cryst. Growth Des. 2011, 11(12), 5574-5591.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2933.39
TSCA
No

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