I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.
Mainly employed inorganic synthesis. They are starting materials for the condensation reactions. Homoallylic alcohol is readily available from the regiospecific ring opening of commercially available ethyl (S)-oxiranyl acetate with the cuprate derived from vinylmagnesium bromide and copper bromide-dimethyl sulfide complex in 88 % yield.
A. J. Durbetaki. Direct Titration of Oxirane Oxygen with Hydrogen Bromide in Acetic Acid. Anal. Chem.. 1956, 28(12), 2000-2001.
P. Andrew Evans Prof. Dr.,; William J. Andrews. A Sequential Two-Component Etherification/Oxa-Conjugate Addition Reaction: Asymmetric Synthesis of (+)-Leucascandrolide A Macrolactone. Angewandte Chemie. 2008, 120 (29),5506-5509,.
Gefahrenhinweise (EU): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.