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80875-98-5 - (2S,3aS,7aS)-Octahydroindole-2-carboxylic acid, 98% - H27894 - Alfa Aesar

H27894 (2S,3aS,7aS)-Octahydroindole-2-carboxylic acid, 98%

CAS-Nummer
80875-98-5
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 69,73
5g 204,97
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(2S,3aS,7aS)-Octahydroindole-2-carboxylic acid, 98%

MDL
MFCD07782125

Chemische Eigenschaften

Formel
C9H15NO2
Molmasse
169.22
Schmelzpunkt
266° dec.
Optical Rotation
-50 (c=1 in methanol)
Löslichkeit
Soluble in methanol and water.

Anwendungen

An intermediate in the synthesis of Perindopril. The completely diastereoselective α-alkylation of oxazolidinone provides a very convenient and concise route to enantiopure α-tetrasubstituted derivatives of this Oic stereoisomer.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents. Store at -20°C.

Literaturverweise

Francisco J. Sayago,; M. Isabel Calaza,; Ana I. Jiménez,; Carlos Cativiela. A straightforward route to enantiopure α-substituted derivatives of (2S,3aS,7aS)-octahydroindole-2-carboxylic acid. Journal name. 2009, 65(27) ,5174-5180.

Francisco J. Sayago,; M. Isabel Calaza,; Ana I. Jiménez,; Carlos Cativiela. Versatile methodology for the synthesis and α-functionalization of (2R,3aS,7aS)-octahydroindole-2-carboxylic acid. Tetrahedron. 2008, 64(1), 84-91.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2933.99
TSCA
No

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