Protonated diacetone alcohol and protonated 4- hydroxy-3-methyl-2-butanone undergo vinylation and colli- sion-induced dehydration as the only primary reactions, the product of the former reaction consisting of up to 40% of the total product ion distribution.
Masahiro Hirama,; Kenshu Fujiwara,; Kuniyoshi Shigematu,; Yoshimasa Fukazawa.The 10-membered ring analogs of neocarzinostatin chromophore: design, synthesis and mode of decomposition. J. Am. Chem. Soc. 1989, 111 (11), 4120-4122.
Xiaoyu Liu,; Harvey E. Jeffries,; Kenneth G. Sexton. Atmospheric Photochemical Degradation of 1,4-Unsaturated Dicarbonyls. Environ. Sci. Technol. 1999, 33 (23),4212-4220.
Gefahrenhinweise (EU): H227-H315-H319-H335
Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves and eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.