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628-92-2 - Cycloheptene, 96%, stab. with 0.1% BHT - H29062 - Alfa Aesar

H29062 Cycloheptene, 96%, stab. with 0.1% BHT

CAS-Nummer
628-92-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 95,40
25g 289,00
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Cycloheptene, 96%, stab. with 0.1% BHT

MDL
MFCD00004156
EINECS
211-060-4

Chemische Eigenschaften

Formel
C7H12
Molmasse
96.17
Siedepunkt
112-115°
Flammpunkt
-7°(19°F)
Dichte
0.833
Brechungsindex
1.458
Löslichkeit
Insoluble in water.

Anwendungen

Cycloheptene was used in one-pot synthesis of 1,2/3-triols from the allylichydroperoxides catalyzed by zeolite-confined osmium(0) nanoclusters. It is a raw material in organic chemistry and a monomer in polymer synthesis. Copper (1) triflate catalyzes the photodimerization of the simple nonconjugated unstrained olefins, cyclopentene, cyclohexene, and cycloheptene, but not cyclooctene or acyclic olefins.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, acids. May react exothermically with reducing agents to release hydrogen gas.

Literaturverweise

Göksu H, et al. J. . One-pot synthesis of 1, 2/3-triols from the allylic hydroperoxides catalyzed by zeolite-confined osmium (0) nanoclusters. Mol. Catal. A: Chem.. 2013, 378 142-147.

Robert G. Salomon,; Kirsten Folting,; William E. Streib,; Jay K. Kochi. Copper(I) catalysis in photocycloadditions. II. Cyclopentene, cyclohexene, and cycloheptene. J. Am. Chem. Soc. 1974, 96(4),1145-1152.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225

Highly flammable liquid and vapour.

Sicherheitshinweise: P210-P280a-P240-P241-P303+P361+P353-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2902.19
TSCA
No

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