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1013-88-3 - Benzophenone imine, 95% - H30110 - Alfa Aesar

H30110 Benzophenone imine, 95%

CAS-Nummer
1013-88-3
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 52,90
25g 136,00
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Benzophenone imine, 95%

MDL
MFCD00001760

Chemische Eigenschaften

Formel
C13H11N
Molmasse
181.23
Siedepunkt
151-153°/10mm
Dichte
1.08
Brechungsindex
1.6180
Löslichkeit
Insoluble in water.

Anwendungen

Useful in the preparation of nitrile ylide dimers.Benzophenone imine as ammonia surrogate. As intermediate material for synthesis of organic chemicals. Catalytic enantioselective alkylation of the benzophenone imine of glycine t-butyl ester using phosphazene (Schwesinger) bases and chiral quaternary ammonium salts yields either enantiomer of amino acid derivatives in excellent yield.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literaturverweise

Suzanne Fergus et. al. Nitrile ylide dimerization: investigation of the carbene reactivity of nitrile ylides.. Journal of Organic Chemistry. 2004, 69 (14),4663-4669.

C. R. Noller. Diphenylmethane inime hydrochloride. Org. Synth. 10 (28).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2925.29
TSCA
No

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