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926-02-3 - tert-Butyl vinyl ether, 98%, stab. with ca 0.1% N,N-diethylaniline - 2-Methyl-2-vinyloxypropane - H30770 - Alfa Aesar

H30770 tert-Butyl vinyl ether, 98%, stab. with ca 0.1% N,N-diethylaniline

CAS-Nummer
926-02-3
Synonyme
2-Methyl-2-vinyloxypropane

Größe Preis ($) Menge Verfügbarkeit
5g 52,98
25g 157,46
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tert-Butyl vinyl ether, 98%, stab. with ca 0.1% N,N-diethylaniline

MDL
MFCD00048246
EINECS
618-860-6

Chemische Eigenschaften

Formel
C6H12O
Molmasse
100.16
Siedepunkt
75-76°
Flammpunkt
-17°(1°F)
Dichte
0.762
Brechungsindex
1.3990
Löslichkeit
Miscible with alcohol, carbon disulfide, chloroform and diethyl ether. Slightly miscible with water.

Anwendungen

tert-Butyl vinyl ether is used in the synthesis of 3-tert-Butoxycyclobutanone by reacting with ketene using zinc(II) chloride as a catalyst. It acts as an intermediate for the functional vinyl monomer.

Bemerkungen

Incompatible with strong oxidizing agents.

Literaturverweise

Han, D.; Cao, H.; Li, J.; Li, M.; Li, X.; He, M.; Hu, J. Theoretical studies on the mechanisms and rate constants for the hydroxylation of n-butyl, iso-butyl and tert-butyl vinyl ethers in atmosphere. Struct. Chem. 2015, 26 (3), 713-729.

Najera, C.; Sansano, J. M.; Yus, M. 1,3-Dipolar cycloadditions of azomethine imines. Org. Biomol. Chem. 2015, 13 (32), 8596-8636.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H402-H412

Highly flammable liquid and vapour. Harmful to aquatic life. Harmful to aquatic life with long lasting effects.

Sicherheitshinweise: P210-P273-P243-P403

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid release to the environment. Take precautionary measures against static discharge. Store in a well-ventilated place.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2909.19
TSCA
Yes

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