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7550-45-0 - Titanium(IV) chloride, 1M soln. in toluene - Titanium tetrachloride - Titanic chloride - H31808 - Alfa Aesar

H31808 Titanium(IV) chloride, 1M soln. in toluene

CAS-Nummer
7550-45-0
Synonyme
Titanium tetrachloride
Titanic chloride

Größe Preis ($) Menge Verfügbarkeit
100ml 41,40
500ml 139,00
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Titanium(IV) chloride, 1M soln. in toluene

MDL
MFCD00011267

Chemische Eigenschaften

Formel
Cl4Ti
Molmasse
189.69
Flammpunkt
8°(46°F)
Dichte
0.964
Sensitivität
Moisture Sensitive
Löslichkeit
Reacts with water.

Anwendungen

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines

Bemerkungen

Moisture Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers

Literaturverweise

Min Shi.; Jian-Kang Jiang.; Yan-Shu Feng. Titanium(IV) Chloride and the Amine-Promoted Baylis-Hillman Reaction. Org. Lett. 2000, 16, (2), 2397-2400.

Min Shi.; Yan-Shu Feng. Titanium(IV) Chloride and Quaternary Ammonium Salt Promoted Baylis-Hillman Reaction. J. Org. Chem. 2001, 66, (2), 406-411.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H304-H361-H373-H314-H336

Highly flammable liquid and vapour. May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage. May cause drowsiness or dizziness.

Sicherheitshinweise: P210-P260-P201-P261-P301+P310-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2827.39
TSCA
Yes

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