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33527-91-2 - Tris(2-dimethylaminoethyl)amine, 99+% - Me6TREN - H31853 - Alfa Aesar

H31853 Tris(2-dimethylaminoethyl)amine, 99+%

CAS-Nummer
33527-91-2
Synonyme
Me6TREN

Größe Preis ($) Menge Verfügbarkeit
5g 118,00
25g 394,00
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Tris(2-dimethylaminoethyl)amine, 99+%

MDL
MFCD00015607

Chemische Eigenschaften

Formel
C12H30N4
Molmasse
230.40
Siedepunkt
70-71°/0.5mm
Brechungsindex
1.4540
Sensitivität
Air Sensitive & Hygroscopic
Löslichkeit
Miscible with water.

Anwendungen

Tris(2-dimethylaminoethyl)amine is used as an atom transfer radical polymerization (ATRP) ligand for the creation of telechelic polymers. It is a tripodal polyamine ligand and forms complexes with group 1 metals, which is used in alkali-metal-mediated synthetic applications. Further, it is involved in the macrocyclization processes by reacting with tripodal esters in methanol to give tricyclic cryptands.

Bemerkungen

Hygroscopic. Air sensitive. Incompatible with oxidizing agents, acids.

Literaturverweise

Samanta, S. R.; Cai, R.; Percec, V. A rational approach to activated polyacrylates and polymethacrylates by using a combination of model reactions and SET-LRP of hexafluoroisopropyl acrylate and methacrylate. Polym. Chem. 2015, 6 (17), 3259-3270.

Citek, C.; Herres-Pawlis, S.; Stack, T. D. P. Low Temperature Syntheses and Reactivity of Cu2O2 Active-Site Models. Acc. Chem. Res. 2015, 48 (8), 2424-2433.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2921.29
TSCA
Yes

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