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54109-16-9 - 2-Bromo-2'-(trifluoromethyl)acetophenone, 97% - 2-(Trifluoromethyl)phenacyl bromide - H32032 - Alfa Aesar

H32032 2-Bromo-2'-(trifluoromethyl)acetophenone, 97%

CAS-Nummer
54109-16-9
Synonyme
2-(Trifluoromethyl)phenacyl bromide

Größe Preis ($) Menge Verfügbarkeit
250mg 53,30
1g 86,50
5g 359,00
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2-Bromo-2'-(trifluoromethyl)acetophenone, 97%

MDL
MFCD03094304

Chemische Eigenschaften

Formel
C9H6BrF3O
Molmasse
267.04
Schmelzpunkt
24-32°
Löslichkeit
Slightly soluble in water.

Anwendungen

The sulfonyl urea thus obtained was used directly in the following condensation with 4-(trifluoromethyl)phenacyl bromide. Upon heating, benzenesulfinic acid ammonium salt might react with 2-(trifluoromethyl)phenacyl bromide to give β-keto sulfone. In Rap-Stoermer condensation reation.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literaturverweise

Jason Xiang,; Manus Ipek,; Vipin Suri,; Walt Massefski,; Ning Pan,; Ying Ge,; May Tam,; Yuzhe Xing, James F. Tobin,; Xin Xuc,; Steve Tama. Synthesis and biological evaluation of sulfonamidooxazoles and β-keto sulfones: selective inhibitors of 11β-hydroxysteroid dehydrogenase type I. Bioorganic & Medicinal Chemistry Letters. 2005, 15 (11),2865-2869.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2914.79
TSCA
No

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