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73035-16-2 - 3-Acetylbenzenesulfonyl chloride, 97% - H32447 - Alfa Aesar

H32447 3-Acetylbenzenesulfonyl chloride, 97%

CAS-Nummer
73035-16-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 75,50
5g 251,00
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3-Acetylbenzenesulfonyl chloride, 97%

MDL
MFCD03424979

Chemische Eigenschaften

Formel
C8H7ClO3S
Molmasse
218.66
Schmelzpunkt
42-43°
Sensitivität
Moisture Sensitive

Anwendungen

Classical acetamidomalonate addition/decarboxylative hydrolysis as the key step for the generation of the amino acidic moiety starting from 4-ethylsulfonyl-α-bromoacetophenone prepared in two steps from commercially available 4-acetyl-benzenesulfonyl chloride. This then treated with sodium sulfite in basic aqueous conditions yielded the sodium sulfinate.

Bemerkungen

Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, bases.

Literaturverweise

Roberto Pellicciari Prof.1,; Rosa C. Rizzo Dr.,; Gabriele Costantino Prof.,; Maura Marinozzi Prof.,; Laura Amori Dr.,; Paolo Guidetti Dr.,; Hui-Qiu Wu Dr.,; Robert Schwarcz Dr. Modulators of the Kynurenine Pathway of Tryptophan Metabolism: Synthesis and Preliminary Biological Evaluation of (S)-4-(Ethylsulfonyl)benzoylalanine, a Potent and Selective Kynurenine Aminotransferase II (KAT II) Inhibitor. ChemMedChem. 2006, 1 (5), 528-531.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2914.79
TSCA
No

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