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102308-32-7 - (S)-(-)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde, 95% - (S)-(-)-3-tert-Butoxycarbonyl-2,2-dimethyloxazolidine-4-carboxaldehyde - Garner's Aldehyde - H51049 - Alfa Aesar

H51049 (S)-(-)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde, 95%

CAS-Nummer
102308-32-7
Synonyme
(S)-(-)-3-tert-Butoxycarbonyl-2,2-dimethyloxazolidine-4-carboxaldehyde
Garner's Aldehyde

Größe Preis ($) Menge Verfügbarkeit
250mg 59,84
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(S)-(-)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde, 95%

MDL
MFCD00209557

Chemische Eigenschaften

Formel
C11H19NO4
Molmasse
229.27
Dichte
1.06
Brechungsindex
1.4450
Sensitivität
Air Sensitive
Löslichkeit
Slightly soluble in water.

Anwendungen

It is used to prepare γ-aminophosphonates (N-arylamide phosphonates as subtype-selective sphingosine 1-phosphate receptor agonists and antagonists. It is also used to synthesize N-sulfonylated propargylglycine derivatives as metalloproteinase inhibitors. Also widely utilized in the asymmetric synthesis of natural products.

Bemerkungen

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literaturverweise

Foss, F., et al. Synthesis and biological evaluation of γ-aminophosphonates as potent, subtype-selective sphingosine 1-phosphate receptor agonists and antagonists. Bioorganic & Medicinal Chemistry. 2007, 15(2), 663-677.

Natchus, M., et al. Development of New Carboxylic Acid-Based MMP Inhibitors Derived from Functionalized Propargylglycines. J. Med. Chem. 2001, 44(7), 1060-1071.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,4371
Beilstein
3591324
Harmonized Tariff Code
2934.99
TSCA
No

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