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121359-48-6 - 2-(Tri-n-butylstannyl)thiazole, 96% - Tri-n-butyl-2-thiazolyltin - H51090 - Alfa Aesar

H51090 2-(Tri-n-butylstannyl)thiazole, 96%

CAS-Nummer
121359-48-6
Synonyme
Tri-n-butyl-2-thiazolyltin

Größe Preis ($) Menge Verfügbarkeit
1g 117,00
5g 490,00
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2-(Tri-n-butylstannyl)thiazole, 96%

MDL
MFCD01319057

Chemische Eigenschaften

Formel
C15H29NSSn
Molmasse
374.17
Siedepunkt
307-309°
Dichte
1.19
Löslichkeit
Not miscible or difficult to mix.

Anwendungen

Used as reagent for arylation of thiazole by Stille cross-coupling.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literaturverweise

Rüdiger Wittenberg; Jiri Srogl; Masahiro Egi; and Lanny S. Liebeskind. Ketone Synthesis under Neutral Conditions. Cu(I) Diphenylphosphinate-Mediated, Palladium-Catalyzed Coupling of Thiol Esters and Organostannanes. Org. Lett,. 2003, 5(17), 3033-3035.

Hao Li; Hao Yang; and Lanny S. Liebeskind. Synthesis of High Enantiopurity N-Protected α-Amino Ketones by Thiol Ester-Organostannane Cross-Coupling Using pH-Neutral Conditions. Org. Lett., 2008, 10(19), 4375-4378.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H312-H315-H319-H372-H400-H410

Toxic if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Sicherheitshinweise: P273-P280-P309-P310-P501a

Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2934.10
TSCA
No

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