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6921-34-2 - Benzylmagnesium chloride, 1M in MeTHF - H51154 - Alfa Aesar

H51154 Benzylmagnesium chloride, 1M in MeTHF

CAS-Nummer
6921-34-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100ml 38,11
500ml 127,44
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Benzylmagnesium chloride, 1M in MeTHF

MDL
MFCD00000469

Chemische Eigenschaften

Formel
C7H7ClMg
Molmasse
150.89
Sensitivität
Air & Moisture Sensitive
Löslichkeit
It reacts violently with water.

Anwendungen

Benzyl magnesium chloride is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). It is also used as organic chemical synthesis intermediate.

Bemerkungen

Air & moisture sensitive. Incompatible with oxidizing agents and bases.

Literaturverweise

M.York Darensbourg; H.L.Conder; D.J.Darensbourg; C.Hasday. Electronic and steric control of reactions of benzylmagnesium chloride with substituted metal carbonyls. J. Am. Chem. Soc. 1973, 95, (18),5919-5924

 

Maliakel P.Balu; Gurdeep Singh; Hiriyakkanavar Ila; Hiriyakkanavar Junjappa. Cycloaromatization of δ-oxoketendithioacetals with benzylmagnesium chloride: A novel naphthalene annelation reaction. Tetrahedron Letters. 1986, 27, (1),117-120

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Sicherheitshinweise: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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