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807329-97-1 - Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF - H51156 - Alfa Aesar

H51156 Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF

CAS-Nummer
807329-97-1
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100ml 78,48
500ml 280,80
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Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF

MDL
MFCD07784514

Chemische Eigenschaften

Formel
C3H7ClMg.LiCl
Molmasse
145.24
Flammpunkt
-17°(1.4°F)
Dichte
0.951
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Miscible with ethers and amines.

Anwendungen

Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

Bemerkungen

Air and moisture sensitive. Incompatible with oxidizing agents and water.

Literaturverweise

Huddleston, N. E.; Roy, A.; Bilbrey, J. A.; Zhao, Y.; Locklin, J. Functionalization of Reactive End Groups in Surface-Initiated Kumada Catalyst-Transfer Polycondensation. Macromol. Symp. 2015, 351 (1), 27-36.

Hickey, M. J.; Kingston, L. P.; Allen, P. H.; Johnson, T.; Wilkinson, D. J. A short expedient synthesis of [14C]Ticlopidine. J. Labelled Compd. Radiopharm. 2014, 57 (3), 172-174.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H261-H314

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage.

Sicherheitshinweise: P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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