Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

100-59-4 - Phenylmagnesium chloride, 1M in MeTHF - H51157 - Alfa Aesar

H51157 Phenylmagnesium chloride, 1M in MeTHF

CAS-Nummer
100-59-4
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100ml 33,99
500ml 142,14
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Phenylmagnesium chloride, 1M in MeTHF

MDL
MFCD00000464

Chemische Eigenschaften

Formel
C6H5MgCl
Molmasse
136.86
Flammpunkt
-17°(1.4°F)
Sensitivität
Air & Moisture Sensitive
Löslichkeit
It reacts violently with water.

Anwendungen

Phenylmagnesium chloride is used primarily to add an iso-propyl group to carbonyl groups. This reagent can also be used as a strong base in aprotic solvents. It is also used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Bemerkungen

Air & moisture sensitive. Incompatible with heat.

Literaturverweise

Bogdan Boduszek; Henry J.Shine; T.Krishnan Venkatachalam. Reactions of phenylmagnesium chloride and phenyllithium with thianthrene cation radical perchlorate. Evidence for electron transfer: formation and decomposition of 5-substituted thianthreniumyl perchlorates. J. Org. Chem. 1989, 54, (7),1616-1626

 

Henry Gilman; Nina B. St. John. The preparation of phenylmagnesium chloride. Recueil des Travaux Chimiques des Pays-Bas. 1930, 49, (8),717-723

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H261-H314-H302-H312-H333

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Harmful if swallowed. Harmful in contact with skin. May be harmful if inhaled.

Sicherheitshinweise: P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
Yes

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf