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23719-80-4 - Cyclopropylmagnesium bromide, 0.5M in MeTHF - H51158 - Alfa Aesar

H51158 Cyclopropylmagnesium bromide, 0.5M in MeTHF

CAS-Nummer
23719-80-4
Synonyme

Größe Preis ($) Menge Verfügbarkeit
50ml 142,00
100ml 224,00
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Cyclopropylmagnesium bromide, 0.5M in MeTHF

MDL
MFCD00672094

Chemische Eigenschaften

Formel
C3H5BrMg
Molmasse
145.28
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Reacts with water.

Anwendungen

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Bemerkungen

Air and Moisture Sensitive, store away from air and water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literaturverweise

H. M. Walborsky; Christoph Zimmermann. The surface nature of Grignard reagent formation.J. Am. Chem. Soc.,1992, 114(13), 4996-5000.

Chutian Shu; Kanwar Sidhu; Li Zhang; Xiao-jun Wang; Dhileepkumar Krishnamurthy; and Chris H. Senanayake. Palladium-Catalyzed Cross-Coupling of Cyclopropylmagnesium Bromide with Aryl Bromides Mediated by Zinc Halide Additives. J. Org. Chem., 2010, 75(19), 6677-6680.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H261-H313-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. May be harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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