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873-77-8 - 4-Chlorophenylmagnesium bromide, 1M in MeTHF - H51163 - Alfa Aesar

H51163 4-Chlorophenylmagnesium bromide, 1M in MeTHF

CAS-Nummer
873-77-8
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100ml 39,20
500ml 158,00
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4-Chlorophenylmagnesium bromide, 1M in MeTHF

MDL
MFCD00009926

Chemische Eigenschaften

Formel
C6H4BrClMg
Molmasse
215.76
Sensitivität
Air & Moisture Sensitive
Löslichkeit
It reacts violently with water.

Anwendungen

4-Chlorophenylmagnesium bromide is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Bemerkungen

Air & moisture sensitive. Incompatible with oxidizing agents.

Literaturverweise

Boyd R.Taylor; Glenn A.Fox; Lousia J.Hope-Weeks; Robert S.Maxwell; Susan M.Kauzlarich; Howard W.H.Lee. Solution preparation of Ge nanoparticles with chemically tailored surfaces. Materials Science and Engineering: B. 2002, 96, (2),90-93

 

Jacqueline C.Bussolari; Patricia A.McDonnell. A new substrate for the Biginelli Cyclocondensation:? Direct preparation of 5-unsubstituted 3,4-dihydropyrimidin-2(1H)-ones from a β-keto carboxylic acid. J. Org. Chem. 2000, 65, (20),6777-6779

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Sicherheitshinweise: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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