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H51168 3-Fluorophenylmagnesium bromide, 1M in MeTHF

CAS-Nummer
17318-03-5
Synonyme

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3-Fluorophenylmagnesium bromide, 1M in MeTHF

MDL
MFCD00672007

Chemische Eigenschaften

Formel
C6H4BrFMg
Molmasse
199.31
Flammpunkt
-11°(12°F)
Dichte
1.024
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. May form a Precipitate. Store under Argon. Ambient temperatures.
Löslichkeit
It reacts violently with water.

Anwendungen

3-Fluorophenylmagnesium bromide is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Bemerkungen

Air & moisture sensitive. Incompatible with oxidizing agents, acids, bases and alcohols.

Literaturverweise

Sophie Marquais; Michael Arlt. Aryl-aryl cross coupling on a solid support using zinc organic reagents and palladium catalysis. Tetrahedron Letters. 1996, 37, (31),5491-5494

 

Ni Yan; Xiaozhong Liu; Joseph M.Fox. Facially selective and regioselective carbometalation of cyclopropenes by Aryl Grignard Reagents. J. Org. Chem. 2008, 73, (2),563-568

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H302-H314-H318

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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